MCQ Collection
MDCAT Chemistry MCQs
Practice MDCAT Chemistry questions with answers and explanations.
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Correct Answer: D. Vaporization throughout a liquid when vapor pressure equals external pressure
Explanation:
Bubbles can form throughout the liquid at the boiling point.
Lower external pressure lowers boiling temperature.
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Correct Answer: A. A bond formed by side-by-side overlap of parallel orbitals
Explanation:
Pi bonds place electron density above and below the bond axis.
Double and triple bonds contain pi bonding.
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Correct Answer: A. Surface escape of liquid molecules into the gas phase
Explanation:
Evaporation can occur below the boiling point.
Higher-energy surface molecules escape preferentially.
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Correct Answer: B. One sigma and one pi
Explanation:
The first bond between two atoms is sigma.
The second bond is pi.
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Correct Answer: B. Tendency of a liquid surface to minimize area
Explanation:
Cohesive forces pull surface molecules inward.
Stronger intermolecular forces generally increase surface tension.
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Correct Answer: C. One sigma and two pi
Explanation:
A triple bond contains one axial sigma bond.
Two perpendicular pi bonds complete the bond order of three.
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Correct Answer: C. Resistance of a fluid to flow
Explanation:
Viscosity arises from internal friction.
It usually decreases for liquids as temperature increases.
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Correct Answer: D. Attraction involving H bonded to N, O, or F and a lone pair
Explanation:
Hydrogen bonding is stronger than ordinary dipole forces.
It strongly affects boiling point and solubility.
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Correct Answer: D. Pressure is inversely proportional to volume at constant temperature
Explanation:
For a fixed gas sample at constant temperature, PV is constant.
Compression increases pressure.
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Correct Answer: A. Attractions caused by temporary and induced dipoles
Explanation:
Dispersion forces occur in all atoms and molecules.
Their strength generally increases with polarizability.
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Correct Answer: A. Volume is proportional to absolute temperature at constant pressure
Explanation:
Gas volume rises with kelvin temperature at fixed pressure.
Temperature must be on an absolute scale.
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Correct Answer: B. Attractions between permanent molecular dipoles
Explanation:
Polar molecules align partially positive and negative regions.
These attractions affect physical properties.